CCRES Low Carbon Fuels in Aviation

 photo by CCRES  

Flasks of Algae at the CCRES Lab in Zagreb,Croatia

Biofuels are key to industry’s future

 In a bid to reduce its dependency on imported oil and tackle global warming, the EU has committed to raising the share of fuels from renewable sources in transport to 10% by 2020 – including biofuels, hydrogen and green electricity.

For the growing aviation industry, the switch to plant-based fuel is seen as not only environmentally smart, but a sensible financial move in an era or rising conventional fuel prices and worries about supply security.

Biofuel use in passenger aircraft is still a novelty, and industry officials are urging governments to help lift supplies, much as policies in the EU and United States have created a flourishing market in plant-based oils for motor vehicles.

The industry contends that sustainable fuels will reduce emissions even as passenger traffic grows. The airline sector has committed to meet 10% of its overall fuel consumption with biofuels by 2017 – though the goal is ambitious given that it is to account for just 1% by 2015...

Meanwhile, more doubts are being raised about the environmental benefits of biofuels.

The United Nations Environment Programme has warned that even though burning plant-based fuels can produce significantly lower levels of carbon emissions, production and land clearing to make way for new crops “may reduce carbon-savings or even lead to an increase.”

European conservation groups say the EU and European governments should wait to embrace aviation biofuels until there is proof of their environmental benefits.

 ”Given the right conditions, algae can double its volume overnight. Microalgae are the earth’s most productive plants –– 10 to 15 times more prolific in biomass than the fastest growing land plant exploited for biofuel production. While soy produces some 50 gallons of oil per acre per year; canola, 150 gallons; and palm, 650 gallons, algae can produce up to 15,000 gallons per acre per year. In addition, up to 50 percent (or more) of algae biomass (dry weight) is comprised of oil, whereas oil-palm trees—currently the most efficient large-scale source of feedstock oil to make biofuels—yield approximately 20 percent of their weight in oil,” says Zeljko Serdar, President of CCRES

 Airlines have committed to ramping up their use of biofuels in the belief that they can contribute to achieving the sectors pledges on carbon-neutral growth. For 2050, the EU foresees 40% use of "sustainable low carbon fuels" in aviation.

Croatian Center of Renewable Energy Sources (CCRES)

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Carbon capture and consumption

 

Could it Eliminate the Need for Wastewater Aeration?

Algal blooms have always proved a challenge for the water industry. Yet could this organic matter,with the help of wastewater nutrients, be turned into a biofuel and help alleviate fossil fuel shortages? Tom Freyberg investigates the European funded All-Gas project.

First generation biofuels from crops never really bloomed into a fruitful harvest. Opponents criticized using up valuable land to grow crops and fuel the cars of the rich, instead of filling the stomachs of the poor. Second generation biofuels – made from biomass - have proved a lot harder to extract the required fuel and fully crack.

And then along came algae. Unlike first generation biofuels, algae can be grown using land and water not suitable for plant and food production.

Consuming solar energy and reproducing itself, algae generates a type of oil that has a similar molecular structure to petroleum products produced today. As if this wasnt enough – algae growth also consumes carbon dioxide, a known major greenhouse gas (GHG).

As a result of the apparent benefits the race is on to commercialize second and now third generation biofuels, in the case of algae. Continents and companies are putting money where their mouths are to find out how what we thought was simply a green weed growing in the sea could be the answer to inevitable fossil fuel shortages.

Algal culture ponds are used to grow and harvest micro-algae using nutrients contained in wastewater

Earlier this year US President Barack Obama announced that the Department of Energy would make $14 million available to support research and development into biofuels from algae. The Department has suggested that up to 17% of the US imported oil for transportation could be replaced with biofuels derived from the substance.

Meanwhile Europe is going even further and mandating the gradual replacement of fossil fuels to biofuels. An EU Directive stipulates that by 2020 a total of 20% of energy needs should be produced by renewable fuels. A further requirement is that 10% of biofuels need to be met through transport related activities.

Even UK government backed agency the Carbon Trust has forecast that by 2030, algae-based biofuels could replace more than 70 billion litres of fossil fuels used every year around the world in road transportation and aviation.

Nutrients: burden or blessing?

So far, so good. Yet while algae derived biofuels sound like an answer to inevitable fossil fuel shortages, two challenges remain: space and nutrients. The first challenge will be addressed later but on the topic of nutrients, phosphorous and ammonia are required alongside sun light and carbon dioxide to "feed" the algae. And with up to 30% of operating costs at algae farms attributed to buying and adding in such nutrients, its a notable expense.

It is in response to this particular challenge where the wastewater sector could play its part, with untreated effluent being a known source of phosphorous and other nutrients. An EU funded project aims to bring together the challenge and solution and link the water and biofuel industries together.

The €12 million, five-year project is starting at water management company aqualias wastewater treatment plant in Chiclana, Southern Spain and is backed by the European Union as part of its FP7 program – supporting energy-related projects - with six partners.

Called All-Gas, which translates into algae in Spanish, the project will see "algal culture ponds" being used to grow micro-algae using nutrients contained in wastewater, such as phosphorous. A 10-hectare site will eventually be needed for the project. Frank Rogalla, head of R&D at aqualia, says nutrients are abundant in wastewater, so it makes sense to incorporate the two industries.

Traditionally aeration processes at wastewater treatment plants are heavy energy users, accounting for up to 30% of a facilitys operating costs. In the US, according to the Environmental Protection Agency, drinking water and wastewater systems account for between 3% and 4% of national energy consumption alone.

However, Rogalla later told Water & Wastewater International magazine (WWi) that growing algae with wastewater can eliminate the need for aeration, thus reducing energy use.

He said: "We have converted our treatment to anaeraobic pre-treatment, meaning we will generate biogas from the start instead of destroying organic matter, so no aeration will be needed. From the 0.5 kWh [kilowatt-hour] per m³ which you generally spend for aeration, that will be completely gone. We will have a net output of energy from algae conversion either to oils or to gas. So thats why you get this positive output of 0.4 kWh per m³ of wastewater treated."

Rogalla added: "It will not cost more than traditional wastewater treatment, which costs about 0.2 Euros per cubic metre. We think we will use the same operational costs but instead of consuming energy we will produce additional benefit, meaning we generate about 0.2 Euros per cubic metre in additional profit from the fuel. Our aim is to be cost neutral."

So the question has to be asked of how, technically, can the proposed treatment eliminate the need for wastewater aeration? The answer, as Rogalla later tells WWi, is through the initial conversion to biogas.

Compared to nitrification and dentrification to eliminate nutrients in conventional wastewater treatment, a process Rogalla says consumes about 5 kWh/kg Nitrogen during aeration, All-Gas will use an alternative conversion. Firstly anaerobic pre-treatment will convert most organic matter into biogas (CH4 and CO₂). Algae will then take up the nitrogen and phosphorous.

Productive: instead of using traditional nitrification and dentrification processes, organic matter will instead be converted into biogas

As the algae will transform most nutrients into biomass, they will also produce O2 in the process, as CO₂ is taken up and oxygen released in their metabolic process. As a result, according to Rogalla, aeration is not necessary. Most organic carbon is transformed into energy (via biogas), nutrients are incorporated into algae, which produce oxygen for any polishing action necessary.

An overview of aqualias wastewater treatment plant in Chiclana, Southern Spain

"It only seems logical to use the wastewater nutrients to grow algae biomass; on the one hand saving the aeration energy, on the other hand the algae fertilizer and cleaning wastewater without the occurrence of useless sludge, but producing biofuels and added value instead," Rogalla adds.

CROATIAN CENTER of RENEWABLE ENERGY SOURCES (CCRES)

  special thanks to U.S. Department of Energy | USA.gov

  and WaterWorld, Industrial WaterWorld

Space challenges

Addressing the second challenge of space requirements to harness algae ponds, for a commercial scale operation its estimated that a 10 hectare site is required (roughly 10 football pitches). Yet when compared to the oil yields of other crops, algae still proves favourable.

Data from US-based National Renewable Energy Laboratory (NREL) show that oil yields from soybeans work out at 400 litres/hectare/year, which compares to 6,000 for palm oil and theoretically, a potential 60,000 for microalgae. For barrels/hectare/year, the same comparison yields 2.5 for soybeans, 36 for palm oil and a minimum of 360 for microalgae.

As predictions go, the production of 60,000 litres of biofuel from only one hectare of algae is optimistic compared aqualias aims for the Europe project. If a target set by the EU is reached, then each hectare should produce 20,000 litres of biodiesel. This, the firm says, compares to 5000 litres of biofuel per hectare per year for biofuels such as alcohol from sugar cane or biodiesel from palm oil.

The Spanish project also hopes to use produced biogas from the anaerobic pre-treatment and raw wastewater organic matter as car fuel, with each hectare touted to treat about 400 m³ per day.

Statistics to one side, the challenge of space remains. Booming urban populations are expanding closer to rural wastewater treatment plants but at the same communities insist on an out of sight, out of mind rule when it comes to infrastructure that treats their waste. Rogalla does not think the land issue could impede the development of algae ponds to the majority of wastewater treatment plants. "Algae ponds of course can be put on marginal lands, or even on rooftops," he adds. "In rural areas extensive oxidation ponds for wastewater treatment are not uncommon, not to mention the often unused land areas as buffer zones around wastewater treatment plants.

Biogas generated from wastewater could mean the 0.5 kWh per m3 usually spent on aeration wont be required

"As we do not claim that all fuel can be made from biofuel on land, but only where possible wastewater should be turned into biofuel (excluding mostly big cities), the land issue seems secondary."

Carbon capture and consumption

One further benefit that has made algae growth attractive compared to other fuels is its consumption of Greenhouse Gases (GHG), namely CO₂, in order to grow. While captured carbon consumed by algae will inevitably be released later when used as a fuel in cars, it could still be a step in the right direction in reducing the impact of a world still firmly grasping CO₂ emitting fuel sources.

An article entitled Algal Biofuels: The Process from NREL in a Society for Biological Engineering journal suggests that over two billion tons of CO₂ could be captured by growing algae on the space equivalent to the entire U.S. soybean crop of 63.3 million acres.

Power plants and cement kilns appear to be an ideal match for algae growth, then. Yet, in order for All-Gas to attract seven million Euros worth of funding for its project, the CO₂ had to come from renewable sources. Any fossil fuel burning plants were not permitted, as Denise Green, manager of biofuels across Europe and Africa from Hart Energy Consulting tells WWi.

"This particular call was restricted to projects in which the carbon dioxide supply for the algae cultivation was provided by renewable applications, excluding carbon dioxide from fossil fuel installations," she says.

"However I see no reason why future funding for algae projects could not be provided for research into algae as part of the solution for CO₂ capture for zero emission power generation. If there are objections to using algae from fossil fuel installations for transportation fuels, there are other industries for which algae can be used where this may not be an issue."

Project roll out and commercialisation

The project will be implemented in two stages, with a prototype facility being used to confirm the scale of the full-size plant during the first two years. Once the concept has been proven in full-scale ponds, a 10 hectare site will be developed and operated at commercial scale during the next three years.

Rogalla suggests the project could be rolled out among aqualias existing facilities along the Mediterranean belt, including Italy, Portugal, Egypt and even South America, all of which have "favourable conditions, meaning the climate is advantageous and the land is available".

Clearly, the conversion of algae to fuel is possible and has been demonstrated on a laboratory scale. It could hold the potential to turn a new leaf for biofuels haunted by their unsuccessful and much criticized first generation brothers. The real interest for the water sector should be the pipe dream of the project to eliminate aeration and turn existing wastewater treatment facilities into biofuel production centres.

The pivotal outcome of the project will be cost. This was proved in the well documented closure of the US Department of Energys algae research programme in 1996 after nearly 20 years of work. At the time it was estimated that the $40-60/bbl cost of producing algal oil just couldnt compete with petroleum for the foreseeable future.

However, it is the additional methane extracted from raw wastewater and algae residue that differentiates this project. Its not just reliant upon biodiesel produced from the algae. All-Gas has the chance to spearhead Europe into proving that algae biofuel, through the help of wastewater, could eventually be more competitive on a per barrel price with traditional oil.

CCRES ALGA PROJECT 

part of 

Croatian Center of Renewable Energy Sources (CCRES)

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Official Movie THRIVE What On Earth Will It Take

If you value what is presented in this movie, please go to http://thrivemovement.com/ where you can support Thrive Movement by making a donation. You will also find more in-depth information on each of the subjects discussed in the movie, learn about Critical Mass initiatives supported by Thrive, and connect with others who are waking up and taking action.

Film Synopsis:
THRIVE is an unconventional documentary that lifts the veil on whats REALLY going on in our world by following the money upstream -- uncovering the global consolidation of power in nearly every aspect of our lives. Weaving together breakthroughs in science, consciousness and activism, THRIVE offers real solutions, empowering us with unprecedented and bold strategies for reclaiming our lives and our future.

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CO2 Capture and Storage CCS

  

 

Everything you wanted to know about
CO2 Capture and Storage (CCS), but had no one to ask .

 

 

1. What is CCS?

CO2 Capture and Storage (CCS) describes a technological process by which the carbon dioxide (CO2) generated by large stationary sources - such as coal- fired power plants, steel plants and oil refineries - is prevented from entering the atmosphere.

That’s because it enables at least 90% of these CO2 emissions to be captured, then stored in geological formations – safely and permanently – deep underground (at least 800m). In fact, it uses the same natural trapping mechanisms which have already kept huge volumes of oil, gas and CO2 underground for millions of years.

Currently, all of the CO2 produced by these large stationary sources is released into the atmosphere – directly contributing to global warming.

2. Why is it a critical technology for combating climate change?

CCS is the single biggest lever to combat climate change (compared to, for example, energy efficiency which requires many different actions). In fact, CCS has the potential to address almost half of the world’s current CO2 emissions.

Experts estimate that by 2050, CCS could reduce annual CO2 emissions by 0.6 to 1.7 billion tonnes in the EU and by 9 to 16 billion tonnes worldwide. The upper end of this range would require its application to all fossil fuel power plants and to almost all other large industrial emitters – with the large volumes of hydrogen produced used for transport fuel.

3. What other benefits will CCS provide?

In addition to its potential to reduce CO2 emissions on a massive scale, CCS will also provide greater energy security – by making the burning of Europe’s abundant coal reserves more environmentally acceptable and reducing its dependency on imported natural gas. CCS could also facilitate the transition to a hydrogen economy through the production of large volumes of clean hydrogen which that could be used for electricity or transport fuel.

EU demonstration efforts on CCS will not only demonstrate the EU’s commitment to delivering on its own CO2 reduction targets, but spur other countries to do the same – especially large CO2 emitters, such as China, India and the US. As a global solution to combating climate change, CCS could therefore also give a major boost to the European economy – promoting technology leadership, European competitiveness and creating jobs.

4. How does CCS work?

CCS consists of three stages:
i. Capture: CO2 is captured and compressed at the emissions site.
ii. Transport: The CO2 is then transported to a storage location.
iii. Storage: The CO2 is permanently stored in geological formations, deep underground.

Each of these stages – capture, transport and storage – can be accomplished in different ways.

i. Capture processes:

    Post-combustion: CO2 is removed from the exhaust gas through absorption by selective solvents.
    Pre-combustion: The fuel is pre- treated and converted into a mix of CO2 and hydrogen, from which the CO2 is separated. The hydrogen is then used as fuel, or burnt to produce electricity.
    Oxy-fuel combustion: The fuel is burned with oxygen instead of air, producing a flue stream of CO2 and water vapour without nitrogen; the CO2 is relatively easily removed from this stream.

ii. Transport options:
Pipelines are the main option for large-scale CO2 transportation, but shipping and road transport are also possibilities.

iii. Storage options:

    Deep saline aquifers (saltwater-bearing rocks unsuitable for human consumption)
    Depleted oil and gas fields (with the potential for Enhanced Oil Recovery)

5. How long has CCS been in existence?

Although there are currently no fully integrated, commercial-scale CCS projects for power plants in operation, many of the technologies that make up CCS have been around for decades:

    CO2 capture is already practised on a small scale, based on technology that has been used in the chemical and refining industries for decades.
    Transportation is also well understood: it has been shipped regionally for over 17 years, while a 5,000km network has been operating in the USA for over 30 years for Enhanced Oil Recovery.
    Small-scale CO2 storage projects have been operating successfully for over a decade, e.g. at Sleipner (Norway), Weyburn (Canada) and In Salah (Algeria). The industry can also build on knowledge obtained through the geological storage of natural gas, which has also been practised for decades.

6. What’s the next step?

CCS technology now needs to be scaled up – including full process integration and optimisation – with demonstration projects of a size large enough to allow subsequent projects to be at commercial scale. This will also build public confidence in CCS as more and more people see that CO2 storage is safe and reliable.

7. Why should we use CCS, given its link to fossil fuels?

Scientists have confirmed that unless we stabilise CO2- equivalent concentrations at their current level of 450 parts per million (ppm), average global temperature is likely to rise by 2.4ºC to 6.4ºC by 2100. If we fail to keep below 2ºC, devastating – and irreversible – climate changes will occur.

This means reducing CO2-equivalent emissions by 50% by 2030. But with world energy demand expected to double by 2030 and renewable energies to make up ~30% of the energy mix by this date, only a portfolio of solutions will achieve this goal. This includes energy efficiency, a vast increase in renewable energy – and CCS.

Around 750 new coal power plants are already planned for the period 2005–2018, totaling more than 350 Gigawatt (GW), of which 50 will be in Europe, almost 300 in China, 200 in India and 50 in the US.

8. Why is it so important to deploy CCS as soon as possible?

Time is of the essence. Any delay in the roll-out of CCS could not only lead to unnecessary CO2 emissions but additional costs, as instead of being able to apply it to the current pipeline of coal plants, a retrofit would be required, increasing the cost of achieving the same emissions reduction. With decisions on the building of new power plants being made now in Europe, it is vital that we are not locked into an infrastructure that is not optimised for CCS.

Indeed, every year that CCS is delayed is a missed opportunity to reduce CO2 emissions. Today, we have ~450 parts per million (ppm) CO2 equivalent in the atmosphere, with concentration rising at over 2 ppm per annum. The Intergovernmental Panel on Climate Change states that if we are to avoid major climate change effects, we must not exceed this 450 ppm. Delaying the implementation of CCS by just 6 years would mean CO2 concentrations increasing by around 10 ppm by 2020.

9. If we are at such a critical phase, why isn’t it already being deployed?

The incremental costs of the first large-scale CCS demonstration projects will be exceptionally high – too high to be fully justifiable to company shareholders.

That’s because all ‘First Movers’ will incur:

    Unrecoverable costs from making accelerated investments in scaling up the technology.
    Market risk due to uncertainty over:
    a) which CCS technologies will prove the most successful
    b) the future CO2 price and
    c) construction and operational costs.

Based on an independent study recently undertaken by McKinsey and Company, it is estimated that the total incremental costs of 10-12 CCS demonstration projects would be €7 billion - €12 billion.

Industry has already declared its willingness to cover both the base costs of the power plant (without CCS) and a major portion of the risks of implementing these CCS demonstration activities. Given that it will bring incalculable benefits to both the public and European industry and that these projects are inherently loss-making, public funding has therefore been provided to support 12 industrial-scale CCS projects. Without this, commercialisation will be severely delayed – until at least 2030 in Europe.

10. Why are public funds needed for CCS demonstration projects?

Currently, a CCS demonstration project would be a loss-making enterprise for industry, given the current price of implementing and using the technology; the current price of carbon; and uncertainty surrounding long-term viability and profitability. No shareholder can therefore be expected to fund it fully at this stage.

The typical cost of a demonstration project is likely to be in the range €60-90 per tonne of CO2 abated. Recent analyst estimates for Phase II of the European Union Emissions Trading Scheme (EU ETS) range from €30 to €48 per tonne of CO2 and, at this stage, similar levels are assumed beyond Phase II (up to 2030). In this range, the carbon price is insufficient for demonstration projects to be “stand-alone”, commercially viable.

Assuming that CCS demonstration projects would cost between €60 and €90 per tonne of CO2, and projecting a median carbon price of €35 per tonne of CO2, there is an “economic gap” of €25-€55 per tonne of CO2 per project. This corresponds to around €500 million - €1.1 billion, expressed as a Net Present Value (NPV) over the lifespan of a 300MW size power plant. The range depends on variations in specific project variables, such as capture technology and capex, transport distance and storage solutions.

11. The UK and the Netherlands are well on their way to implementing CCS demonstration projects – won’t these be enough to make the technology commercially viable?

As it is not yet known which CCS technologies will prove the most successful, it is vital that the full range is tested – including higher-risk technologies – optimised across projects and locations. As each region has its own challenges, local demonstration is also important in order to maximise public and political support.

As importantly, EU CCS demonstration efforts will ensure that cross-border projects – where CO2 is stored in a different country or region to where it is captured – are not excluded. As capture and storage locations are unevenly distributed throughout Europe, cross-border pipelines will play a crucial role in the wide-scale deployment of CCS and the development of clusters in major industrial areas as the next key step.

12. How much will it cost to retrofit CCS technology to existing power plants?

In general, retrofitting an existing power plant would lead to a higher cost for CCS, but these are highly dependent on specific site characteristics, including plant specifications, remaining economic life and overall site layout. For this reason, no generalisation or “reference case” would be meaningful.

There are four main factors likely to drive the cost increase for retrofits:

    The higher capex (capital costs) of the capture facility: the existing plant configuration and space constraints could make adaption to CCS more difficult than for a new build.
    The installation’s shorter lifespan: the power plant is already operating so where (for example) a new plant with CCS may run for 40 years, the capture facility of a 20 year-old plant is likely to have only a 20 year life, reducing the “efficiency” of the initial capex.
    There is a higher efficiency penalty, leading to a higher fuel cost when compared to a fully integrated, newly-built CCS plant.
    There is the “opportunity cost” of lost generating time, because the plant would be taken out of operation for a period to install the capture facility.

13. How can we accelerate the building of CCS projects?

Building a CCS project is a lengthy process: a fully integrated project can take 6.5-10 years before it becomes operational. However, Final Investment Decision can only be made once permits have been awarded across the entire value chain. In the case of CO2 storage, this can take as long as 6.5 years. In such a scenario, even a commercial project started as early as 2016 would not itself become operational until 2024.

Ideally, 10-12 CCS demonstration projects should be operational by 2015. The first early commercial projects should be operational by 2020, with the remaining demonstration projects sufficiently advanced for early commercial projects to be ordered from 2020 onwards. Some 80-120 large- scale CCS projects could therefore be operational in Europe by 2030.

There are several ways we can fast-track the building of CCS projects:

    Starting a commercial project as early as possible during the building of the demonstration project so that – for example – build can start after just one year of the demo being in operation.
    Accelerating feasibility studies etc.
    Making faster investment decisions
    Shortening the tender process
    Introducing special measures to shorten the permitting process.

Some projects, by their very nature, will of course be quicker to build than others, e.g. retrofitting existing power plants with CCS; using well-known oil and gas fields with infrastructure and seismic data already available; those with only a short distance from the power plant to the storage site, etc.

14. How much CO2 can be captured using CCS?

One 900 MW CCS coal-fired power plant can abate around 5 million tonnes of CO2 a year. If, as projected, 80-120 commercial CCS projects are operating in Europe by 2030, they would abate some 400 million tonnes of CO2 per year.

By 2050, CCS could reduce annual CO2 emissions by 0.6 to 1.7 billion tonnes in the EU and by 9 to 16 billion tonnes worldwide. The upper end of this range would require its application to all fossil fuel power plants and to almost all other large industrial emitters – with the large volumes of hydrogen produced used for transport fuel.

15. Isn’t more energy utilised where CCS is implemented?

The absolute efficiency penalty, estimated at around 10% for the reference case (meaning plant efficiency drops from 50% to around 40%), drives an increase in fuel consumption and does require an over- sizing of the plant to ensure the same net electricity output.

However, next-generation technology - such as ultra-supercritical 700°C technology for boilers, coupled with drying in the case of lignite - will achieve a 50% level of overall plant efficiency. While this technology is not currently available, it is expected to be when early commercial CCS projects are built around 2020.

16. Where will CO2 be stored?

The regional distribution and cost of storage in Europe will play an important role in any roll-out of CCS. Most experts agree that depleted oil and gas fields and deep saline aquifers have the largest storage potential.

Depleted oil and gas fields
Depleted oil and gas fields are well understood and around a third of total oil and gas field capacity in Europe is estimated to be economically useable for CO2 storage. With an estimated capacity for 10 to 15 billion tonnes of CO2, this is sufficient for the lifetime of around 50 to 60 CCS projects. However, most of these fields are located offshore in northern Europe and the transportation to and storage of CO2 in these fields (excluding capture) is around twice as costly as onshore fields.

Deep saline aquifers
While much less work has been done to map and define deep saline aquifers, most sources indicate that their capacity should be sufficient for European needs overall. Preliminary conservative estimates by EU GeoCapacity indicate that Europe can store some 136 billion tonnes of CO2 - equivalent to around 70 years of current CO2 emissions from the EU’s power plants and heavy industry. At the higher end of these estimations, EU GeoCapacity estimates some 380 billion tonnes of CO2 could be stored in Europe alone.

17. Storing enormous quantities of CO2 underground must present some risk?

The geological formations that would be used to store CO2 diffuse it, making massive releases extremely unlikely. Indeed, because the CO2 becomes trapped in the tiny pores of rocks, any leakage through the geological layers would be extremely slow, allowing plenty of time for it to be detected and dealt with. In fact, it would not raise local CO2 concentrations much above normal atmospheric levels.

Higher concentration leaks could come from man-made wells, but the oil and gas industry already has decades of experience in monitoring wells and keeping them secure. Storage sites will not, of course, be located in volcanic areas.

18. But won’t CO2 storage increase the likelihood of seismic activity?

A detailed survey takes place to identify any potential leakage pathways before a CO2 storage site is selected. If these are discovered, then the site will not be selected. In areas where some natural seismic activity is already taking place, we can ensure that the pressure on the CO2 does not exceed the strength of the rock by making the volume of CO2 stored relative to that of the storage site. CO2 storage has even proved to be robust in volcanic areas: in 2004, a storage site in Japan endured a 6.8 magnitude earthquake with no damage to its boreholes and no CO2 leakage. But then CO2 has remained undisturbed underground for millions of years – despite thousands of earthquakes.

19. How will we know if the CO2 is leaking?

Before a CO2 storage site is chosen, a detailed survey takes place to identify any potential leakage pathways. If these are found to exist then the site will not be selected. In Europe, underground gas storage (natural gas and hydrogen) has an excellent safety record, with sophisticated monitoring techniques that are easily adaptable to CCS. On the surface, air and soil sampling can be used to detect potential CO2 leakage, whilst changes underground can be monitored by detecting sound (seismic), electromagnetic, gravity or density changes within the geological formations.

The risk of leakage through man-made wells is expected to be minimal because they can easily be monitored and fixed, while CO2 leaking through faults or fractures would be localised and simply withdrawn; and, if necessary, the well closed.

20. Who will be liable for CO2 storage sites over the long-term?

As the CO2 will remain stored underground indefinitely, long-term liability will follow the example set by the petroleum industry, whereby the state assumes liability after a regulated abandonment process. Indeed, EU law governing the safe and permanent storage of CO2 has already been approved and is currently being implemented at national level.

21. Large stationary emitters of CO2 also include refineries, steel and cement plants - how are they linked into what the EC is doing?

The EC encourages the deployment of CCS in other sectors, as 25% of all European CO2 emissions addressable by CCS come from refineries and the cement, iron and steel industries.

 

The European CCS Demonstration Project Network

The EC has established a Network of CCS demonstration projects to generate early benefits from a coordinated European action.
CCS demonstration projects fulfilling minimum qualification criteria are invited to join the Network and benefit from its operations.
The Network allows early-movers to exchange information and experience from large-size industrial demonstration of the use of CCS technologies, to maximise their impact on further R&D and policy making, and optimise costs through shared collective actions.
It is envisaged that, as the Network evolves, its EU-wide, integrating and binding role may be reinforced and complemented by other measures in support of further development of CCS technologies, building towards the establishment of a European Industrial Initiative.

To help fulfil the potential of CO2 Capture and Storage (CCS), the European Commission is sponsoring and coordinating the world’s first network of demonstration projects, all of which are aiming to be operational by 2015. The goal is to create a prominent community of projects united in the goal of achieving commercially viable CCS by 2020.
The CCS Project Network fosters knowledge sharing amongst the demonstration projects and leverage this new body of knowledge to raise public understanding of the potential of CCS. This accelerates learning and ensures that we can assist CCS to safely fulfil its potential, both in the EU and in cooperation with global partners.

CCS Project Network Advisory Forum

To guarantee that the Network is valuable to the wider energy community in Europe, an annual Advisory Forum has been established to review progress and specify the knowledge that can most usefully be generated by the CCS Project Network.

• The first Advisory Forum meeting was held in Brussels on 17 September 2010.
  Read more..
• The second Advisory Forum Meeting was held on 16 June 2011 in Brussels. Read more..

CCS World News

• 2012-07-18 - Carbon capture would create substantial challenges, witnesses say at energy ...
• 2012-07-18 - Opinions Divided on Climate Change and CCS in Saskatchewan
• 2012-07-18 - Planned Tees CCS project could be in line for EU cash
• 2012-07-13 - Yorkshire leads race for €1.5bn EU carbon capture funding
• 2012-07-16 - Codexis releases enzyme CO2 capture results
• 2012-07-16 - U.S. DOE advancing Hydrogen Energy plant in California
• 2012-07-16 - Yorkshire leads race for €1.5bn EU carbon capture funding ...
• 2012-07-15 - UK Don Valley project leads EU funding bid
• 2012-07-15 - Alberta projects get funding boost
• 2012-07-13 - Don Valley leads UK CCS charge for €1.5bn EU funds
• 2012-07-13 - EU says up to 1.5 billion euros ready for low-carbon investment
• 2012-07-12 - Anglo mines to become carbon neutral, CCS-aware by 2030
• 2012-07-12 - Clean coal tech is ready, but theres a catch

Membership of the CCS Project Network is open to all European projects that are at a sufficient scale and level of maturity that will generate valuable output and knowledge about industrial-scale CCS demonstration.
The application process for membership of the Network is designed to be as simple and transparent as practicable, but sufficiently robust to ensure that all members are large-scale demonstration projects at a similar level of maturity.
Project developers may submit applications at any time to demonstrate that they fulfil the eligibility criteria, can provide evidence of the maturity of the project, commit to knowledge sharing and agree to the Network organisation and procedures. The qualification criteria and application process are described in the Qualification Criteria document. The Network is open to all qualifying projects and will not distinguish between EU-funded and non-EU funded projects.

Eligibility Criteria

Projects in the Network shall have sound plans to demonstrate the full CCS value chain by 2015 and shall fulfil the following technical criteria:

• The CCS project shall for a fossil fuel-fired power plant have a minimum gross production of 250MWe before CO2 capture and compression
• The CCS project shall for an industrial plant realise a minimum of 500kt per year of stored CO2
• The CO2 capture rate shall not be less than 85% of the treated flue gas stream
• The project, i.e. the plant to which CCS is applied, shall be located within the European Economic Area (EEA)

Knowledge Sharing

Projects in the Network are committed to knowledge sharing with similar projects and other stakeholders in order to help accelerate CCS deployment and raise public engagement, as described in the Knowledge Sharing Protocol document.

Key documents

European CCS Demonstration Project Network Qualification Criteria
European CCS Demonstration Project Network Knowledge Sharing Protocol

Learn more about CCS

To learn more about CCS, please have a look at the following videos, kindly provided by ZEP:

http://www.ccsnetwork.eu/index.php?p=videos

CROATIAN CENTER of RENEWABLE ENERGY SOURCES (CCRES)
special tanks to

Daniel Rennie
Global CCS Institute
Actualis, Level 2
21 & 23 Boulevard Haussmann
PARIS 75009 France

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Jose Manuel Hernandez
Programme Manager - EU Policies
European Commission

CROATIAN CENTER of RENEWABLE ENERGY SOURCES (CCRES)

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The power of Omega 3 oils

Algae omega-3 fatty acids provide significant health and development benefits during life in the womb. Health and cognitive benefits for omega-3s continue throughout life.

Omega-3 oils

 Essential fatty acids are fatty acids critical to the good health and development of fetuses and newborns. Fetal life and early infancy are the periods of rapid brain, eyes, heart, respiratory, central nervous system, and immune system development and maturation. Omega-3s enhance these growth phases and help children avoid major organ disorders. Newborns may get omega-3 fatty acids from mother’s milk, (if the mother absorbs omega-3s in her diet), from the child’s diet, or from supplements.

Neither humans nor animals can synthesize omega-3 oils because bodies lack the desaturase enzymes required for their production. Therefore, if the mother’s diet is deficient in omega-3s, the infant will not benefit from the essential early growth and development support from long chain fatty acids.

Omega-3s improve Neuron Signaling

Omega-3 oils Omega-3s improve Neuron Signaling

Clinical signs of essential fatty acid deficiency include a dry scaly rash, decreased growth in infants and children, slow or abnormal brain, eye and heart development, increased susceptibility to infection and poor wound healing. Fatty acid deficiency causes pathologies similar to malnutrition.

Most foods contain some fat, even vegetables, because fats play a critical role in metabolism. Fat provides a reliable source of energy as well as an effective depot for stored energy. Fats play an important role in cell membranes, helping to govern nutrients that enter and exit cells during metabolism. When incorporated into phospholipids, fatty acids affect cell membrane properties such as fluidity, flexibility, permeability, and the activity of membrane bound enzymes.

Research shows that omega-3 fatty acids reduce inflammation and may help lower risk of chronic diseases such as heart disease, cancer, and arthritis. Omega-3s are highly concentrated in the brain and appear to be important for cognitive (brain memory and performance) and behavioral function. Studies have shown that infants who do not get enough omega-3 fatty acids from their mothers during pregnancy are at risk for developing vision, brain and nerve problems. Symptoms of omega-3 fatty acid deficiency include fatigue, poor memory, dry skin, heart problems, mood swings or depression, and poor circulation.

In a recent study, prenatal algal DHA supplementation – 600 mg DHA taken from 14 weeks gestation until delivery – increased DHA blood levels in both the mother and the newborn, as well as increased infant birth weight, length, and head circumference. The DHA supplements improved fetus growth and organ development significantly. Other studies have found that prenatal DHA deficiency may limit infants’ development potential.

The DHA Intake and Measurement of Neural Development (DIAMOND) study found that supplementation with DHA and ARA omega fatty acids from 18 months to six years of age provided significant cognitive benefits. DIAMOND also found that DHA supplementation provided developmental benefits evident to six years of age.

Algae polyphenol extracts have anti-diabetic effects through the modulation of glucose-induced oxidative stress. The extracts slow starch-digestive enzymes such as alpha-amylase and alpha-glucosidase.  The plentiful soluble dietary fibers in algae help avoid obesity and diabetes. The total fiber content of several algae species, (~6 g/100g), is greater than that of fruits and vegetables promoted today for their fiber content: prunes (2.4 g), cabbage (2.9 g), apples (2.0 g), and brown rice (3.8 g).

The body uses cholesterol as the starting point to make estrogen, testosterone, vitamin D, and other vital compounds. Fats also serve as biologically active molecules that influence how muscles respond to insulin. Various forms of fats, especially Omega-3s, can accelerate or cool down inflammation.

EPA and DHA

Long chained polyunsaturated fatty acids, (PUFA) eicosapentaenoic acid, EPA, and docosahexaenoic acid, DHA, manage and moderate inflammation and many other cellular functions. These fats influence signaling in cells and the brain and therefore affect mood and behavior.

The US National Institute of Health’s MedlinePlus lists many medical conditions for which EPA alone, or in concert with other omega-3 sources, is known or thought to be an effective treatment. Most medical interventions derive from omega-3 oils’ ability to lower inflammation or enhance cell signaling.

(Left) Anchovy harvested for Fish Oil, (Right) Algae with Omega-3

Omega-3s are often obtained in the human diet by eating oily fish or fish oil— e.g., cod liver, herring, mackerel, salmon, menhaden and sardine. It is also found in human breast milk. Fish do not synthesize Omega-3s, but concentrate it from the algae they consume. Omega-3 rich microalgae are cultivated as a commercial source by a few companies such as Martek and Algae Biosciences. Microalgae, and supplements derived from algae, are excellent sources of EPA and DHA, since fish often contain toxins such as mercury and pesticides due to pollution.

DHA comprises 40% of the polyunsaturated fatty acids (PUFAs) in the brain and 60% of the PUFAs in the retina. Fifty percent of the weight of a neuron’s plasma membrane is composed of DHA. DHA is selectively incorporated into retinal cell membranes and postsynaptic neuronal cell membranes, where it plays important roles in vision and nervous system function. DHA is richly supplied during breastfeeding, and DHA levels are high in breast milk. In humans, DHA is either obtained from the diet or synthesized from eicosapentaenoic acid, (EPA).

Cognitive development

Children that are not exposed to omega-3s in the womb display a significant mental deficit that persists throughout their lives. The human brain requires Omega-3 oils for normal growth and development.

(Left) Human Brain, (Right) Isochrysis Algae with Oil

Review studies suggest that omega-3s positively affect pre-natal neurodevelopment. However, this cognitive-enhancing effect sometimes diminishes post-natally with maturation. Few studies have examined the cognitive effects of omega-3s through childhood, young adulthood, and middle age. At later ages, multiple studies found evidence suggesting that omega-3s can protect against neurodegeneration and possibly reduce the chance of developing cognitive impairment.

Several variables confound PUFA supplements including heredity, diet, mother’s health, and socioeconomics. Supplement treatments in medical studies typically use 1,000 mg of omega-3 per day.

Another important finding is that too much omega-6 oil (found in vegetable oils, nuts and seeds), in the diet may interfere with the action of omega-3. Omega-6 seems to compete with Omega-3 PUFA for the desaturase enzymes. Therefore, medical researchers suggest that maximum value of omega-3 supplements will occur if the diet minimizes omega-6 intake.

Summary

Omega-3 fatty acids can enhance fetal life and give children a better start in life with stronger brains, eyes, hearts and respiratory systems. Pregnant women and nursing mothers have the opportunity to gift strong cognitive development to their newborns with either several servings of fish per week or the recommended 1,000 mg of omega-3 supplements per day.

CCRES special thanks to  AlgaeIndustryMagazine.com

CROATIAN CENTER of RENEWABLE ENERGY SOURCES (CCRES)

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62M to Biofuels Industry

CROATIAN CENTER of RENEWABLE ENERGY SOURCES (CCRES)

  special thanks to U.S. Department of Energy | USA.gov

As part of President Obama’s Blueprint for a Secure Energy Future, he directed the Navy, USDA and DOE to collaborate to support commercialization of “drop-in” biofuel substitutes for diesel and jet fuel. Competitively priced drop-in biofuels, he said, will help improve America’s energy security, meeting the fuel needs of U.S. armed forces, as well as the commercial aviation and shipping sectors. The recent announcement of an available $30 million in funding promotes speeding the development of biofuels for military and commercial transportation. The Funding Opportunity Announcement (FOA) is available.

The U.S. Department of Agriculture (USDA), Navy and Department of Energy are announcing $30 million in federal funding to match private investments in commercial-scale advanced drop-in biofuels. The Energy Department is also announcing a total of $32 million in new investments for earlier stage research that will continue to drive technological breakthroughs and additional cost reductions in the industry.

This funding opportunity is made possible through the Defense Production Act (DPA), an authority that dates back to 1950 and has been used to boost industries such as steel, aluminum, titanium, semiconductors, beryllium, and radiation-hardened electronics.

    “…through this DPA effort the nation will be able to harvest an aviation biofuels industry to satisfy the world’s needs, not just our U.S. military.” — USDA Secretary Tom Vilsack

The new funding comprises a two-phased approach, with government and industry sharing in the cost. In Phase 1, applicants will submit a design package and comprehensive business plan for a commercial-scale biorefinery, identify and secure project sites and take additional required steps spelled out in the announcement. Awardees selected to continue into Phase 2 will submit additional information for the construction or retrofit of a biorefinery.

Agencies participating in this initiative will make additional funding requests to Congress to support the initiative, including President Obama’s FY 2013 budget request of $110 million.

“This is an important time for the biofuels industry to step up and show the Department of the Navy how they have developed biofuels that are certified and certifiable for military use,” said USDA Secretary Tom Vilsack. “The ability for U.S. industry to make, create and innovate has never been more important to our national and energy security. I know that through this DPA effort the nation will be able to harvest an aviation biofuels industry to satisfy the world’s needs, not just our U.S. military.”

The Energy Department has also announced new investments in earlier stage biofuels research that complement the commercial-scale efforts announced by the Navy and USDA. Totaling $32 million, these early-stage, pre-commercial investments are the latest steps in the Obama Administration’s efforts to advance biofuels technologies to continue to bring down costs, improve performance, and identify new effective, non-food feedstocks and processing technologies.

“Advanced biofuels are an important part of President Obama’s all-of-the-above strategy to reduce America’s dependence on foreign oil and support American industries and American jobs,” said Secretary Chu. “By pursuing new processes and technologies for producing next-generation biofuels, we are working to accelerate innovation in a critical and growing sector that will help to improve U.S. energy security and protect our air and water.”

The new funding announced by DOE includes $20 million to support innovative pilot-scale and demonstration-scale biorefineries that could produce renewable biofuels that meet military specifications for jet fuel and shipboard diesel using a variety of non-food biomass feedstocks, waste-based materials and algae. These projects may support new plant construction, retrofits on existing U.S. biorefineries or operation at plants ready to begin production at the pilot- or pre-commercial scale. This investment will also help federal and local governments, private developers and industry collect accurate data on the cost of producing fuels made from biomass and waste feedstocks. The full funding solicitation is available.

In addition, the Energy Department also announced $12 million to support up to eight projects focused on researching ways to develop bio-based transportation fuels and products using synthetic biological processing. Synthetic biological processing offers an innovative technique to enable efficient, cost-saving conversion of non-food biomass to biofuels. These projects will develop novel biological systems that can enhance the breakdown of raw biomass feedstocks and assist in converting feedstocks into transportation fuels.

The projects will be led by small businesses, universities, national laboratories and industry and will seek to overcome various technical and scientific barriers to cost-competitive advanced biofuels and bioproducts. The full funding opportunity announcement is available.

CROATIAN CENTER of RENEWABLE ENERGY SOURCES (CCRES)

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Biomass as an organic renewable energy source

The U.S. Department of Energy has just released this video to educate people on the research, industry and government’s efforts to develop biomass as an organic renewable energy source; employing agriculture and forest residues, energy crops, and algae to take the place of conventional fuels like gasoline, diesel, and jet fuel.

CCRES Algae Team

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Capture the Carbon Dioxide

 Capture the Carbon Dioxide

In nature, photosynthesis uses the energy in sunlight to split water into carbon dioxide and hydrogen. A typical plant cell relies on a series of electron carriers, which create a photosynthetic circuit that allows plants to capture the carbon dioxide they need, and then convert it into the biomass that fuels cell growth. At the same time, plants produce hydrogen, a molecule that can be used in a variety of renewable and sustainable fuel technologies, but that is also expensive to produce in large quantities and currently involves non-renewable natural gas reformation.

A photosynthetic organism such as green algae tends to use solar energy to generate either fixed carbon or hydrogen—while this is fine for growth, it is not particularly efficient for making greater quantities of hydrogen. Facing this challenge, NREL researchers wondered if they could find ways to boost the hydrogen-making capacity of photosynthesis. They posed a key question: What controls the partitioning of electrons between these two competing metabolic pathways?

A team from NREL, along with colleagues from the Massachusetts Institute of Technology and Tel Aviv University, set out to answer this question. They hypothesized that they could engineer the process by "rewiring" algaes catalytic circuits, or pathways. To do so, they would replace the normal hydrogen-producing enzyme, hydrogenase (H2ase), with a ferredoxin and hydrogenase fusion protein. They speculated that inserting this kind of a fusion protein into this reaction path could divert more electrons into hydrogen production and push the algae into making more hydrogen and fixing less carbon dioxide. If successful, this engineered photosynthetic circuit could potentially increase efficiencies and thus bring down the price of hydrogen. In its more than 30-year history of innovation, NREL has been a leader in working with green algae for hydrogen and biofuel production, as well as with finding ways to speed renewable fuels to market to help meet the nations clean energy goals. It is this expertise that encouraged MITs Iftach Yacoby to partner with NREL, which enabled the researchers to collaborate on technical innovations such as the CdTe-H2ase.

During NRELs work with green algae, the labs own Senior Scientist Paul King and other researchers worked with hydrogenase enzymes as a key component of the photosynthetic hydrogen production equation. These biological catalysts can convert electrons and protons into hydrogen gas, or convert hydrogen into electrons and protons. For this work, the team chose to use in vitro tests under anaerobic conditions. They were able to demonstrate how the hydrogenase and other enzymes compete to regulate whether algae uses the solar energy it captures through photosynthesis to produce carbon compounds or hydrogen. As they studied these interactions, they were able to devise a procedure to engineer the proteins that compose electron transfer circuits. 

The first element of their strategy was based on their hypothesis that they could have more of the electrons go to hydrogen if they altered the composition to replace hydrogenase with a ferredoxin-hydrogenase fusion. In the anaerobic test tubes, the team confirmed that the photosynthetic circuit can switch from capturing carbon dioxide to producing hydrogen by substituting the fusion. The hydrogen production was carried out in the presence of the CO₂ fixation enzyme ferredoxin:NADP-oxidoreductase (FNR). This process is a biological model for using solar power to convert water into hydrogen. The basis for this switch was modeled as two new Fd-hydrogenase circuits (boxes 1 and 2, Figure 2), and a reduced level of FNR activity modeled as a third circuit (box 3, Figure 2). 

King considered these results promising, because they suggest that fusion is an engineering strategy to improve hydrogen production efficiencies, and might be useful in resolving the biochemical mechanisms that control photosynthetic electron transport circuits and product levels from competing pathways. The next phase, already underway, is to introduce the fusion protein into green algae Chlamydomonas and determine if rewiring can take place to improve hydrogen-production efficiencies. Even though this is only one of a number of variables to consider, this strategy has already signaled an avenue to pursue in the drive to reduce the cost of hydrogen fuel and make it cost-competitive for industry.

Enlarge image

Photosynthetic electron transport pathways that support carbon dioxide fixation and hydrogen production. Light-activated PSII extracts electrons from water and transfers them, while parallel circuits couple Fd to either FNR for carbon dioxide fixation or hydrogenase production.
Credit: Paul King, NREL

Enlarge image

Engineering of the hydrogen-producing enzyme to create an Fd-H2ase fusion changes the composition of the hydrogen production circuit to include both direct (box 1) and indirect (box 2) H2 production modes. The CO₂ fixation circuit (box 3) remains open, but operates at a reduced level.
Credit: Paul King, NREL

CCRES special thanks to NREL

NREL is a national laboratory of the U.S. Department of Energy, Office Energy Efficiency and Renewable Energy operated by the Alliance for Substainable Energy, LLC.

CROATIAN CENTER of RENEWABLE ENERGY SOURCES ( CCRES)

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